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We chose dipicolinic acid as a tridentate chelating unit featuring ONO donors to react with lanthanide(III) ions to yield tight and protective N(3)O(6) environments around the lanthanide(III) ions. We immobilized the lanthanide(III)-dipicolinic acid complexes on colloidal mesoporous silica with diameter smaller than 100 nm by a covalent bond grafting(More)
A novel design strategy to synthesize highly ordered hexagonally mesostructured metal-organic framework materials was successfully explored, which means the realization of directly cooperative self-assembly of metal ions, bridging ligands and surfactants in an aqueous system.
A series of new titanium(IV) complexes with symmetric or asymmetric cis-9,10-dihydrophenanthrenediamide ligands, cis-9,10-PhenH(2)(NR)(2)Ti(O(i)Pr)(2) [PhenH(2) = 9,10-dihydrophenanthrene, R = 2,6-(i)Pr(2)C(6)H(3) (2a), 2,6-Et(2)C(6)H(3) (2b), 2,6-Me(2)C(6)H(3) (2c)], cis-9,10-PhenH(2)(NR(1))(NR(2))Ti(O(i)Pr)(2) [R(1) = 2,6-(i)Pr(2)C(6)H(3), R(2) =(More)
We have synthesized a series of catalysts for epoxidation of styrene by immobilizing salicylaldimine transition metal (copper, manganese, and cobalt) complexes on mesoporous silica nanoparticles (MSNs) with diameters of 120-150 nm. The prepared catalysts are characterized by infrared (IR) spectra, thermal gravimetric analyses (TGA), inductively coupled(More)
Novel hierarchical spinous hollow titania hexagonal prisms are prepared through a facile fluorine-free self-template route using Ti2O3(H2O)2(C2O4)·H2O (TC) hexagonal prisms as a precursor. The hollowing transformation can be elucidated by the template-free Kirkendall effect, and diverse nanostructures can also be synthesized during the conversion process,(More)
We have synthesized a series of nanocatalysts with different sizes (50-200 nm) for polymerization of 1,3-butadiene (Bd) by immobilizing salicylaldimine cobalt complexes on the mesoporous silica nanoparticles (MSNs). The prepared catalysts have been characterized by infrared (IR) spectra, thermal gravimetric analyses (TGAs), chemical composition analysis,(More)
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