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A highly sensitive fluorescent turn-on probe specific for methylmercury species as well as inorganic mercury ions has been developed on the basis of mercury ion-promoted hydrolysis of a… Continue Reading
A rational approach to fluorescence turn-on sensing of amino carboxylates is described, which primarily relies on the perturbation of the quenching n−π* transition energy level of a carbonyl… Continue Reading
Abstract A chiral C 2 -symmetric NCN ligand, (5 R ,7 R )-1,3-bis(6,6-dimethyl-5,6,7,8-tetrahydro-5,7-methanoquinolin-2-yl)benzene has been synthesized. A direct cyclometalation of this ligand with K… Continue Reading
A direct cyclometalation of a chiral pyridine derivative, (5R,7R)-5,6,7,8-tetrahydro-6,6-dimethyl-2-phenyl-5,7-methanoquinoline (L), with K 2 PtCl 4 in acetic acid is described. A chiral mononuclear… Continue Reading
A direct cyclometalation of a chiral pyridine derivative, (5R,7R)-5,6,7,8-tetrahydro-6,6-dimethyl-2-phenyl5,7-methanoquinoline (L), with K2PtCl4 in acetic acid is described. A chiral mononuclear… Continue Reading
Homochiral coordination cages, which have two well-defined internal binding sites for ammonium and organoammonium ions, have been constructed by Pd(II)-mediated self-assembly of preorganized tripodal… Continue Reading