Diego del Rio

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Reaction of nitrogen monoxide with a copper(I) complex possessing a tridentate alkylamine ligand gives a Cu(I)–(·NO) adduct, which when exposed to dioxygen generates a peroxynitrite (O=NOO−)–Cu(II) species. This undergoes thermal transformation to produce a copper(II) nitrito (NO2 –) complex and 0.5 mol equiv O2. In the presence of a substituted phenol, the(More)
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