David W. Knoeppel

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A series of one-dimensional arrays of lanthanide-transition metal complexes has been prepared and characterized. These complexes, [(DMF)(10)Ln(2)[Ni(CN)(4)](3)](infinity), crystallize as linear single-strand arrays (structural type A) (Ln = Sm, 1a; Eu, 2a) or double-strand arrays (structural type B) (Ln = Sm, 1b; Eu, 2b) depending upon the conditions(More)
One-dimensional arrays having the general formula {(DMF)(10)Ln(2)[M(CN)(4)](3)}(infinity) [Ln = Sm, Eu, Er, Yb and M = Ni, Pd, Pt] were prepared from the reactions of 2:3 molar ratios of LnCl(3) with K(2)[M(CN)(4)] in DMF (DMF = N,N-dimethylformamide). Under similar conditions using 1:1 molar ratios of SmCl(3) and K(2)[Ni(CN)(4)] in DMF or YbCl(3) and(More)
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