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We consider a model dense colloidal dispersion at the glass transition, and investigate the connection between equilibrium stress fluctuations, seen in linear shear moduli, and the shear stresses under strong flow conditions far from equilibrium, viz., flow curves for finite shear rates. To this purpose, thermosensitive core-shell particles consisting of a(More)
The flow curves, viz. the curves of stationary stress under steady shearing, are obtained close to the glass transition in dense colloidal dispersions using asymptotic expansions in the schematic F₁₂(γ)-model of mode coupling theory. The shear thinning of the viscosity in fluid states and the yielding of glassy states is discussed. At the transition between(More)
We analyze the glassy dynamics of binary mixtures of hard disks in two dimensions. Predictions of the mode-coupling theory (MCT) are tested with extensive Brownian dynamics simulations. Measuring the collective particle density correlation functions in the vicinity of the glass transition, we verify four predicted mixing effects. For instance, for large(More)
In this thesis, starting from a schematic mode-coupling model, the dynamics and the ow behavior of colloidal dispersions under stationary shearing close to the glass transition is analyzed. Both analytical and numerical methods are applied. The most important control parameters of the model are the shear rate and the separation parameter measuring the(More)
We study the influence of composition changes on the glass transition of binary hard disk and hard sphere mixtures in the framework of mode coupling theory. We derive a general expression for the slope of a glass transition line. Applied to the binary mixture in the low concentration limits, this method allows a fast prediction of some properties of the(More)
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