Dave Adams

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Figure S1. Self-supporting hydrogel formation by hSAFs. Vials were (A) incubated for 30 minutes on ice, inverted and then incubated on ice for a further 30 minutes, or (B) incubated for 5 minutes on ice, 25 minutes at 20 ºC, inverted and then incubated for a further thirty minutes at 20 ºC. All samples were 1 mM in each peptide. Microrheology Gel strength(More)
Traditional high-frequency pulse width modulation (PWM) inverters for motor drives have several problems associated with their high frequency switching which produces high voltage change (dV/dt) rates. Multilevel inverters solve these problems because their devices switch at the fundamental frequency. Two different multilevel topologies are identified for(More)
Nanoporous molecular frameworks are important in applications such as separation, storage and catalysis. Empirical rules exist for their assembly but it is still challenging to place and segregate functionality in three-dimensional porous solids in a predictable way. Indeed, recent studies of mixed crystalline frameworks suggest a preference for the(More)
We synthesize a series of imine cage molecules where increasing the chain length of the alkanediamine precursor results in an odd-even alternation between [2 + 3] and [4 + 6] cage macrocycles. A computational procedure is developed to predict the thermodynamically preferred product and the lowest energy conformer, hence rationalizing the observed(More)
The photophysical properties of insoluble porous pyrene networks, which are central to their function, differ strongly from those of analogous soluble linear and branched polymers and dendrimers. This can be rationalized by the presence of strained closed rings in the networks. A combined experimental and computational approach was used to obtain atomic(More)
Linear poly(p-phenylene)s are modestly active UV photocatalysts for hydrogen production in the presence of a sacrificial electron donor. Introduction of planarized fluorene, carbazole, dibenzo[b,d]thiophene or dibenzo[b,d]thiophene sulfone units greatly enhances the H2 evolution rate. The most active dibenzo[b,d]thiophene sulfone co-polymer has a UV(More)
A series of fluorescent probes, including a number of molecular rotors, have been used to follow the self-assembly of dipeptide-based low molecular weight gelators. We show that these probes can be used to gain an insight into the assembly process. Thioflavin T, a commonly used stain for β-sheets, appears to act as a molecular rotor in these gelling(More)
The magnetic-field-induced alignment of the fibrillar structures present in an aqueous solution of a dipeptide gelator, and the subsequent retention of this alignment upon transformation to a hydrogel upon the addition of CaCl2 or upon a reduction in solution pH is reported. Utilising the switchable nature of the magnetic field coupled with the slow(More)
Self-sorting in low molecular weight hydrogels can be achieved using a pH triggered approach. We show here that this method can be used to prepare gels with different types of mechanical properties. Cooperative, disruptive or orthogonal assembled systems can be produced. Gels with interesting behaviour can be also prepared, for example self-sorted gels(More)
Development and testing of a compact basis set for use in effective core potential calculations on rhodium complexes Pyrolysis of 3-­‐azidopropionitrile studied by UV photoelectron and matrix-­‐isolation IR spectroscopies: Formation of ketenimine H2C=C=NH Threshold photoelectron spectroscopy (TPES) of vibrationally excited nitrogen