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Quaternary neptunium compounds: syntheses and characterization of KCuNpS(3), RbCuNpS(3), CsCuNpS(3), KAgNpS(3), and CsAgNpS(3).
The five quaternary neptunium compounds KCuNpS3, RbCuNpS3, CsCuNpS3, KAgNpS3, and CsAgNpS3 (AMNpS3) have been synthesized by the reaction of Np, Cu or Ag, S, and K2S or Rb2S3 or Cs2S3 at 793 K (Rb)Expand
Further evidence for the tetraoxoiodate(V) anion, IO43-: Hydrothermal syntheses and structures of Ba[(MoO2)6(IO4)2O4].H2O and Ba3[(MoO2)2(IO6)2].2H2O
The hydrothermal reaction of MoO3 with BaH3IO6 at 180 °C for 3 days results in the formation of Ba[(MoO2)6(IO4)2O4]·H2O (1). Under similar conditions, the reaction of Ba(OH)2·8H2O with MoO3 andExpand
Mixed-metal uranium(VI) iodates: hydrothermal syntheses, structures, and reactivity of Rb[UO(2)(CrO(4))(IO(3))(H(2)O)], A(2)[UO(2)(CrO(4))(IO(3))(2)] (A = K, Rb, Cs), and
The reactions of the molecular transition metal iodates A[CrO(3)(IO(3))] (A = K, Rb, Cs) with UO(3) under mild hydrothermal conditions provide access to four new, one-dimensional, uranylExpand
Syntheses, structures, physical properties, and electronic properties of some AMUQ3 compounds (A = alkali metal, M = Cu or Ag, Q = S or Se).
The seven new isostructural quaternary uranium chalcogenides KCuUS 3, RbCuUS 3, RbAgUS 3, CsCuUS 3, CsAgUS 3, RbAgUSe 3, and CsAgUSe 3 were prepared from solid-state reactions. These isostructuralExpand
Oxidation state of uranium in A6Cu12U2S15 (A = K, Rb, Cs) compounds.
Black single crystals of A(6)Cu(12)U(2)S(15) (A = K, Rb, Cs) have been synthesized by the reactive flux method. These isostructural compounds crystallize in the cubic space group Ia ̅3d at roomExpand
Structural, electronic, and magnetic properties of UFeS3 and UFeSe3.
Black prisms of UFeS(3) and UFeSe(3) have been synthesized by solid-state reactions of U, Fe, and S or Se with CsCl as a flux at 1173 K. The structure of these isostructural compounds consists ofExpand
Dichalcogenide bonding in seven alkali-metal actinide chalcogenides of the KTh2Se6 structure type.
The solid-state compounds CsTh(2)Se(6), Rb(0.85)U(1.74)S(6), RbU(2)Se(6), TlU(2)Se(6), Cs(0.88)(La(0.68)U(1.32))Se(6), KNp(2)Se(6), and CsNp(2)Se(6) of the AAn(2)Q(6) family (A = alkali metal or Tl;Expand
UTa2O(S2)3Cl6: A ribbon structure containing a heterobimetallic 5d–5f M3 cluster
A new solid-state compound containing a heterobimetallic cluster of U and Ta, UTa{sub 2}O(S{sub 2}){sub 3}Cl{sub 6}, has been synthesized and its structure has been characterized by single-crystalExpand
Structure and electrical resistivity of CeNiSb3
Abstract The ternary antimonide CeNiSb 3 has been prepared from an Sb flux or from reaction of Ce, NiSb, and Sb above 1123 K. It crystallizes in the orthorhombic space group Pbcm with Z =12 andExpand