Learn More
The novel amino(imino)germylene 1 was prepared by the conversion of HNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-imino) with 1 equiv. of Ge[N(SiMe3)2]2. Germylene 1 reacts with B(C6F5)3 to afford the borate salt 2(+)[MeB(C6F5)3](-) in a methyl-abstraction and ring-closing reaction. The conversion of 2 with Fe2(CO)9 furnishes the germylene iron(More)
The reaction of bis(2,6-diisopropylphenyl)imidazolin-2-imine (LH, 1) with Me3N·AlH3 furnishes {μ-LAlH2}2 (2). The marked tendency of 2 to release its hydride substituents is ascribed to the strong electron-donor character of the imidazolin-2-iminato ligand. This is supported by its reactivity study and DFT calculations. In fact, compound 2 was further(More)
The title compound, [Li(4)O(4)(C(12)H(8)BO)(4)(C(4)H(10)O)(4)], features a Li(4)O(4) cube. Each Li atom in the cube is additionally coordinated by a diethyl ether mol-ecule and each O atom in the cube carries a 9-oxa-10-boraanthracene residue. The crystal studied was a non-merohedral twin [twin law (-1 0 0 / 0 0 1 / 0 1 0); the contribution of the major(More)
Mol-ecules of the title compound, [Zn(8)(C(6)F(5))(8)O(4)(C(4)H(10)O)(4)], are located on a special position of site symmetry [Formula: see text]. As a result, there is just one quarter-mol-ecule in the asymmetric unit. The title compound features a Zn(4)O(4) cube. Each Zn atom in the cube carries a pentafluorophenyl substituent. Each O atom is bonded to a(More)
Single crystals of the meta- and para-phenylene-bridged ditopic trihydridoborates (Li(THF)(2))(2)[m-C(6)H(4)(BH(3))(2)] and (Li(THF)(2))(2)[p-C(6)H(4)(BH(3))(2)] have been prepared and investigated by X-ray crystallography. The compounds turned out to be coordination polymers in which each trihydridoborate substituent is connected with one trihydridoborate(More)
  • 1