Damien Weidmann

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A near-infrared diode laser with sample-grating distributed Bragg reflectors was used as a widely tunable spectroscopic source for multispecies chemical sensing. Quartz-enhanced photoacoustic spectroscopy was utilized to obtain high absorption sensitivity in a compact gas cell. CO2, H2O C2H2, and NH3 were monitored. A noise equivalent sensitivity of 8 x(More)
Simultaneous exhaled carbonyl sulfide (OCS) and carbon dioxide concentration measurements in human breath are demonstrated with a compact pulsed quantum-cascade laser-based gas sensor. We achieved a noise-equivalent sensitivity (1sigma) of 1.2 parts per billion by measuring a well-isolated OCS P(11) absorption line in the v3 band at 2057.6 cm(-1) using an(More)
In gonarthrosis with unicompartmental prevalence showing either varus or valgus deformity a correction of the leg-axis is indicated even at old age. The upper transcondylar osteotomy is technically simple and easely tolerated. Weight bearing of the operated leg should be avoided during 6 weeks. A follow-up study of 78 patients aged 70 and more years was(More)
Damien Weidmann The University of Oxford Department of Chemistry The Physical and Theoretical Chemistry Laboratory South Parks Road Oxford, OX1 3QZ, United Kingdom and STFC Rutherford Appleton Laboratory Space Science & Technology Department Harwell Science and Innovation Campus Didcot, OX11 0QX, United Kingdom Abstract. We review the use of both pulsed and(More)
A spectroscopic method of molecular detection based on dispersion measurements using a frequency-chirped laser source is presented. An infrared quantum cascade laser emitting around 1912 cm(-1) is used as a tunable spectroscopic source to measure dispersion that occurs in the vicinity of molecular ro-vibrational transitions. The sample under study is a(More)
We report on the development and performance of a gas sensor based on a quantum cascade laser operating at a wavelength of approximately 10 microns to measure ethylene (C2H4) concentrations by use of a rotational component of the fundamental nu 7 band. The laser is thermoelectrically cooled and operates in a pulsed mode. The influence of pulse-to-pulse(More)
The report of an IUPAC Task Group, formed in 2011 on “Intensities and line shapes in high-resolution spectra of water isotopologues from experiment and theory” (Project No. 2011-022-2-100), on line profiles of isolated high-resolution rotational-vibrational transitions perturbed by neutral gas-phase molecules is presented. The well-documented inadequacies(More)
Following the recent development of a ground-based prototype quantum cascade laser heterodyne radiometer operating in the midinfrared, atmospheric ozone profile retrievals from a solar occultation measurement campaign performed at the Rutherford Appleton Laboratory on 21 September 2006 are presented. Retrieval is based on the optimal estimation method. High(More)
The advent of quantum cascade lasers has provided matured continuously tunable solid state laser sources emitting from mid-infrared to terahertz wavelengths. Such sources, used as local oscillators, offer the practical prospect of aircraft, high altitude platform, and satellite deployment of compact and shot noise limited heterodyne radiometers for Earth(More)
We report spectral linewidth measurements of a 9.1-microm distributed-feedback quantum cascade laser (QCL). The free-running QCL beam was mixed with a waveguide isotopic C18O2 laser onto a high-speed HgCdTe photomixer, and beat notes were recorded from a radio-frequency spectral analyzer. Beating was performed at two operating conditions, first near the QCL(More)