Daisuke Yoshihiro

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Nonracemic silanes possessing a silicon stereocenter have structural similarity to their carbon congeners, but show substantial differences in their physical and electronic properties. Therefore, nonracemic silanes have attracted attention in the fields of synthetic, material, and bioorganic chemistry. Despite their potential importance, nonracemic silanes(More)
A variety of functionalized silacyclopentanes were synthesized by highly enantioselective β-eliminations of silacyclopentene oxides followed by stereospecific transformations. The reaction mechanism of the β-elimination was elucidated by DFT calculations. An in vitro biological assay with an oxy-functionalized silacyclopentane showed substantial binding to(More)
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