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ECE-Type Pincer Complexes of Nickel
Pincer complexes of transition metals have demonstrated valuable catalytic reactivities and desirable properties as functional materials. Much more is known about pincer complexes of noble metals,Expand
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Syntheses, structures, spectroscopy, and chromotropism of new complexes arising from the reaction of nickel(II) nitrate with diphenyl(dipyrazolyl)methane.
The complexes [(dpdpm)Ni(2-NO3)2] (1), [(dpdpm)Ni(2-NO3)(1-NO3)(CH3CN)] (2), [(dpdpm)2Ni(1-NO3)(H2O)]NO3 (3), and [(dpdpm)2Ni(H2O)2][NO3]2 (4) (dpdpm = diphenyl(dipyrazolyl)methane, Ph2C(C3N2H3)2),Expand
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Ni(II) complexes featuring non-metallated pincer-type ligands.
Attempts to prepare pincer-type Ni complexes from the ligands (i-Pr(2)POCH(2))(2)CH(2) and (pz*CH(2))(2)CH(2) (pz* = 3,5-dimethylpyrazol-1-yl) gave instead the complexesExpand
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New Pincer-Type Diphosphinito (POCOP) Complexes of Nickel
This report describes the synthesis, characterization, and reactivities of a new series of pincer-type nickel complexes based on the diphosphinito (POCOP) ligands 1,3-(i-Pr2PO)2C6H4, 1, andExpand
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Me2AlCH2PMe2: a new, bifunctional cocatalyst for the Ni(II)-catalyzed oligomerization of PhSiH3.
The role of methylaluminoxane (MAO) in the Ni-catalyzed dehydrogenative homologation of PhSiH3 has been investigated with a view to designing new cocatalysts possessing well-defined chemicalExpand
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New pincer-type diphosphinito (POCOP) complexes of NiII and NiIII.
This communication reports the synthesis and characterization of the new, pincer-type, square-planar, 16-electron compounds {2,6-(OPPr(i)(2))(2)C(6)H(3)}Ni(II)Br, 1, andExpand
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Group 10 metal indenyl complexes
Abstract This review summarises the synthesis, characterisation, and reactivities of Group 10 metal indenyl complexes reported up to the end of 2001. We begin with a brief summary of the variousExpand
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Regioselective Hydroamination of Acrylonitrile Catalyzed by Cationic Pincer Complexes of Nickel(II)
The cationic pincer-type complexes [{(i-Pr2PCH2CH2)2CH}Ni(NCCH3)][BPh4] (1), [{2,6-(i-Pr2PCH2)2-C6H3}Ni(NCCH3)][BPh4] (2), [{2,6-(i-Pr2PO)2-C6H3}Ni(NCCH3)][BPh4] (3), andExpand
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Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Reaction of the diphosphine ligand i-Pr2P(CH2)5P(i-Pr)2 with NiBr2 at 110 °C gives a mixture of the 16-membered bimetallacycle {i-Pr2P(CH2)5P(i-Pr)2}2Ni2Br4, 1, and the pincer-type complexExpand
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New POCN-Type Pincer Complexes of Nickel(II) and Nickel(III)
Unsymmetrical POC(H)N-type pincer ligands react with NiBr2(NCMe)x to give the complexes (POCN)NiIIBr (POCN= κP,κC,κN-{2-(i-Pr2PO),6-(NR2CH2)-C6H3}; NR2= 3-morpholino (3a), NMe2 (3b), and NEt2 (3c)).Expand
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