D. Suzuki

Publications45
h-index11
Citations789
Highly Influential Citations2
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Synthesis and structure activity relationships of glycine amide derivatives as novel Vascular Adhesion Protein-1 inhibitors.
Vascular Adhesion Protein-1 (VAP-1) is a promising therapeutic target for the treatment of several inflammatory-related diseases including diabetic microvascular complication. We identified glycine… Expand
Selective Preparation of Benzyltitanium Compounds by the Metalative Reppe Reaction. Its Application to the First Synthesis of Alcyopterosin A.
In situ generated (hypo)iodite catalysts for the direct α-oxyacylation of carbonyl compounds with carboxylic acids.
a-Acyloxycarbonyl compounds, which are significant building blocks in synthetic organic chemistry, can traditionally be prepared by the substitution reaction of a-halocarbonyl compounds with alkaline… Expand
One-pot synthesis of metalated pyridines from two acetylenes, a nitrile, and a titanium(II) alkoxide.
Four-component coupling process involving two acetylenes, a nitrile, and a divalent titanium alkoxide reagent, Ti(O-i-Pr)(4)/2i-PrMgCl, directly yielded titanated pyridines in a highly selective… Expand
Titanium Alkoxide-Based Method for Stereoselective Synthesis of Functionalized Conjugated Dienes
Treatment of an internal acetylene such as 1-silyl-1-octyne (3) with a low-valent titanium reagent, (η2-propene)Ti(O-i-Pr)2 (1) readily prepared from Ti(O-i-Pr)4 and i-PrMgCl in situ, generates an… Expand
Facile preparation of various heteroaromatic compounds via azatitanacyclopentadiene intermediates.
Coupling of acetylene, nitrile, and a titanium reagent, Ti(O-i-Pr)(4)/2 i-PrMgCl, generated new azatitanacyclopentadienes in a highly regioselective manner. Their subsequent reaction with… Expand
Metalative Reppe reaction. Organized assembly of acetylene molecules on titanium template leading to a new style of acetylene cyclotrimerization.
Selective syntheses of metalated pyridines from two different unsymmetrical acetylenes, a nitrile, and a titanium(II) alkoxide.
Cyclotrimerization of two different, unsymmetrical acetylenes and p-toluenesulfonylnitrile with a divalent titanium alkoxide reagent, Ti(O-i-Pr)4/2 i-PrMgCl, yielded single pyridyltitanium compounds… Expand
Selective preparation of benzyltitanium compounds by the metalative Reppe reaction. Its application to the first synthesis of alcyopterosin A.
Dialkoxytitanacyclopentadienes, prepared from two different acetylenes and a divalent titanium alkoxide reagent, Ti(O-i-Pr)4/2 i-PrMgCl, reacted with propargyl bromide to give directly benzyltitanium… Expand
Total Synthesis and Stereochemical Assignment of (±)-Sorbiterrin A
A concise, biomimetic approach to sorbiterrin A has been developed employing consecutive Michael additions of a 4-hydroxypyrone to a sorbicillinol derivative and silver nanoparticle-mediated bridged… Expand
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