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Synthesis and structure of and DFT-studies on 1,3,5-[P(O)(i-PrO)2]3C6H3 and its CHCl3 adduct: analysis of the Cl3C–H⋯OP hydrogen bond
Abstract The novel triphosphonic ester 1,3,5-[P(O)(i-PrO)2]3C6H3 (1) was synthesized and fully characterized including single crystal X-ray diffraction analysis. Crystallization in the presence ofExpand
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Polynuclear bismuth-oxo clusters: insight into the formation process of a metal oxide.
The reaction of the bismuth silanolates [Bi(OSiR2R')3] (R = R' = Me, Et, iPr; R = Me, R' = tBu) with water has been studied. Partial hydrolysis gave polynuclear bismuth-oxo clusters whereas amorphousExpand
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Bismuth−Arene π-Interaction: A Combined Experimental and Theoretical Approach
The triorgano bismuth compound [Bi(CH2C6H4Cl-2)3]2 (2) was characterized by an X-ray single-crystal structure analysis, which reveals the formation of a two-dimensional network as a result ofExpand
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[Bi(OSitBuPh2)3]: A Metal Silanolate with a Weak Bismuth ‐ π Arene Interaction
The title compound [Bi(OSitBuPh2)3] (1) was prepared by the reaction of [Bi(OtBu)3] with tBuPh2SiOH in toluene at room temperature. The compound crystallizes in the monoclinic space group P21/n withExpand
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The First Metal‐Oxo Cluster Containing Lithium and Bismuth
The reaction of [Bi(OtBu)3] with LiOSiMe3 gave the heterobimetallic bismuth-oxo cluster [Bi3Li5(μ5-O)2(μ3-OSiMe3)2(μ3-OtBu)2(μ2-OtBu)6] (1) after elimination of Me3SiOSiMe3. The cage compound 1 isExpand
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Synthesis and Characterization of Three Homoleptic Bismuth Silanolates: [Bi(OSiR3)3] (R = Me, Et, iPr)
The bismuth tris(triorganosilanolates) [Bi(OSiR3)3] (1, R = Me; 2, R = Et; 3, R = iPr) were prepared by reaction of R3SiOH with [Bi(OtBu)3]. Compound 1 crystallizes in the triclinic space group withExpand
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Synthesis, structural characterisation, thermal behaviour and electrospray ionisation mass spectrometric studies of bismuth(III) halide complexes with (iso-PrO)2(O)PCH2P(O)(Oiso-Pr)2
Abstract The bismuth halides BiX3 (X=Cl, Br, I) react with the chelating oxygen-coordinating-donor ligand (iso-PrO)2(O)PCH2P(O)(Oiso-Pr)2 (L) to give one-to-one complexes, which have beenExpand
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The Stereochemical Activity of the Lone Pair in [Bi(NO3)3{(iPrO)2(O)PCH2P(O)(OiPr)2}2] — Comparison of Bismuth, Lanthanum and Praseodymium Nitrate Complexes
Five coordination compounds of bismuth, lanthanum and praseodymium nitrate with the oxygen-coordinating chelate ligand (iPrO)2(O)PCH2P(O)(OiPr)2 (L) are reported: [Bi(NO3)3(L)2] (1), [La(NO3)3(L)2]Expand
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