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Oxidation of some primary amines by bromamine‐B in alkaline medium: A kinetic and mechanistic study
The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by sodium N-bromobenzenesulfonamide or bromamine-B (BAB) in sodium hydroxide medium has been
Oxidation of pentoses by sodium-N-bromo-P-toluene sulphonamide : a kinetic and mechanistic study
Abstract Kinetics of oxidation of D-xylose, D-ribose, D-lyxose and L-arabinose by bromamine-T (sodium N-bromo-p-toluene sulphonamide, BAT) was studied in alkaline medium at 30 °C. The rate was
Sodium N-Chlorobenzenesulfonamide as a Selective Oxidant for Hexosamines in Alkaline Medium: A Kinetic and Mechanistic Study.
TLDR
In the proposed mechanism the alkoxy anion of the hexosamine formed in a base-catalyzed reaction at C-1 carbon is subjected to an electrophilic rate-limiting attack by Cl(+) of the oxidant.
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