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On the structure of tert-butyl hypoiodite
On donne trois methodes de preparation de ce compose: reaction de l'hypochlorite de t-butyle avec l'iode, reaction de l'hypochlorite de t-butyle avec les iodures metalliques et reaction du t-butylateExpand
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On the mechanism of the reduction of some ketones by organotin hydrides. Hydride transfer, electron-transfer-hydrogen-atom abstraction, or free radical addition
Reduction de 3 cetones, cyclopropyl phenyl cetone, trifluoro-2,2,2 acetophenone et fluoro-2 acetophenone par l'hydrure de triphenyl-Sn. Obtention de stannylethers. Effet du solvant sur la reactivite
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On the Mechanism of the Reaction of alpha-Substituted Ketones with Allyltributylstannane.
The mechanisms for the reaction of allyltributylstannane with a number of fragmentation probes, alpha-substituted acetophenones, were studied. All reactions were shown to proceed through free radicalExpand
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STRUCTURE AND REACTIONS OF THE SUCCINIMIDYL RADICAL: A DENSITY FUNCTIONAL STUDY
Recent density functionals and a variety of basis sets were employed in the study of three electronic states of the succinimidyl radical in C2v symmetry:  2A1 (σN), 2B1 (πN), and 2B2 (σO). The lowestExpand
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Viscosity-dependent cage reactions. Multiple substitutions in radical-chain chlorinations
The mechanism by which the free-radical clorination of alkanes produces polychlorides has been explained by the assumption that the geminate chlorine atom-chloroalkane pair react in their solventExpand
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