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We report the vibrational signatures of a single H2O molecule occupying distinct sites of the hydration network in the Cs(+)(H2O)6 cluster. This is accomplished using isotopomer-selective IR-IR(More)
We review the role that gas-phase, size-selected protonated water clusters, H(+)(H2O)n, have played in unraveling the microscopic mechanics responsible for the spectroscopic behavior of the excess(More)
We clarify the role of the critical imidazolium C(2)H position (the central C between N atoms in the heterocycle) in the assembly motif of the [EMIM][BF4] ionic liquid by analyzing the vibrational(More)