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- Andrea Melchior, Elena Rillo Peralta, Manuel Valiente, Claudio Tavagnacco, Francesco Endrizzi, M. Tolazzi
- Dalton transactions
- 2013
Thermodynamic parameters of complex formation between d(10) metal ions, such as Zn(2+), Cd(2+), Hg(2+) and Ag(+), and the macrocyclic thioether 1,4,7-trithiacyclononane ([9]AneS3) or the monodentate… (More)
The formation of Cd(II) and Co(II) complexes with N-methylethylenediamine (men) has been studied at 298 K in dimethylsulfoxide (dmso) in an ionic medium set to 0.1 mol dm−3 with Et4NClO4 in anaerobic… (More)
- Daniel Iglesias, Angela Giuliani, +8 authors Paolo Fornasiero
- 2018
Summary Electrochemical oxygen reduction (ORR) is a challenging approach for the sustainable production of hydrogen peroxide (H 2 O 2 ) and is also a reaction of relevance in fuel-cell applications.… (More)
Abstract A new series of inorganic and organometallic cobalt Schiff base complexes containing the tetradentate ligand {[Z-Tyr(3-Ac)-OMe] 2 en} derived from the condensation of two equivalents of… (More)
- M. Victoria Bracamonte, Michele Melchionna, +4 authors Paolo Fornasiero
- 2017
Abstract The importance of sensing hydrogen peroxide (H 2 O 2 ) is due to its ubiquity, being extensively used in industry and also being a biologically relevant side-product of several enzymatic… (More)
- Tiziano Montini, Manuela Bevilacqua, +5 authors Paolo Fornasiero
- 2009
A series of La1−xSrxNi0.6Fe0.4O3 mixed oxides were synthesized by a coprecipitation method, followed by calcination at 1000 °C. Materials with x < 0.100 exhibited a rhombohedral structure similar to… (More)
Abstract Bovine heart cytochrome c was studied through cyclic voltammetry in mixed water–organic solvent solutions under different conditions of temperature and the thermodynamic properties Δ S ° rc… (More)
Abstract The electron transfer (ET) process of progressively unfolded bovine cytochrome c immobilized on different self-assembled monolayers (SAMs) was investigated. Insight is gained on the role of… (More)
- M. Victoria Bracamonte, Michele Melchionna, +6 authors Maurizio Prato
- Chemistry
- 2015
The development of new electrocatalysts for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) at physiological pH is critical for several fields, including fuel cells and… (More)
Polarographic and voltammetric evidences are reported for the production of intermediates superoxo [Rh]OO and hydroperoxo [Rh]OOH derivatives at the electrode surface, in the reduction of dioxygen in… (More)