Christine Walbaum

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The title compound, [Sr(C(14)H(20)O(5))(2)](I(3))(2), obtained by slow evaporation of an ethanol/dichloro-methane solution (1:1) of SrCl(2), benzo-15-crown-5 and I(2), is built of sandwich-like [Sr(benzo-15-crown-5)(2)](2+) cations and isolated linear I(3) (-) anions which are arranged in alternating layers parallel to (010). The triiodide anions are(More)
A reaction of YI 3 , dibenzo-24-crown-8 and iodine in ethanol yielded, as a by-product, red single crystals of (I 2)@(db24c8). pm 3 , Z = 1, R 1 = 0.0301 for 1965 reflections with I 0 > 2σ(I 0), iodine molecules with an I–I distance of 268.39(7) pm, slightly longer than in the gas phase, are included in a matrix of db24c8 molecules.
Salts of alkaline earth metal cations sequestered in dibenzo-18-crown-6 (Db18c6) and benzo-15crown-5 (B15c5), respectively, with I5−, I7− and I82− as the anions, have been synthesized and their crystal structures determined by single-crystal X-ray diffraction. [Ca(Db18c6)(H2O)3](I5)2(Db18c6)(H2O) (1): monoclinic, P21 (no. 4), a = 1322.1(2), b = 1849.1(2), c(More)
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