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A fluorine-substituted pyrrolidinium-based ionic liquid for high-voltage Li-ion batteries.
TLDR
A fluorine-substituted ionic liquid based on a pyrrolidinium cation and a bis(fluorosulfonyl)imide anion was synthesized using a facile one-step reaction and showed good compatibility both in Li and graphite anodes, and superior voltage stability is demonstrated.
Synthesis and characterization of sulfated Gal-β-1,3/4-GlcNAc disaccharides through consecutive protection/glycosylation steps.
We have developed an expeditious procedure to yield large amounts of orthogonally protected Gal-β1,3/4-GlcNAc, which allowed for the systematic introduction of a sulfate group onto the C3/C6
Dynamics of Water in Hierarchical Mesoporous H-ZSM-5 by Fast Field-Cycling NMR Relaxometry
The dynamics of water molecules adsorbed in hierarchical mesoporous H-ZSM-5 was investigated by fast field-cycling NMR relaxometry. Three distinct sites in H-ZSM-5 that can host water molecules,
Au@SnO2 Core-Shell Nanowires: Novel Material for Gas Sensor
Via Vapor-Liquid-Solid (VLS) mechanism, Au@SnO2 core-shell nanowires were fabricated on SiO2 substrates with using of high purity Sn metal on which Au nanoparticles were dispersed. According to HRTEM
Quintuply-bonded dichromium(I) complexes featuring metal-metal bond lengths of 1.74 A.
TLDR
A series of complexes of the form [Cr2{m-h -ArNC(R)NAr}2], which all exhibit very short Cr Cr quintuple-bond lengths of approximately 1.74, are reported, from which metal–metal quintuple bonds are expected.
Remarkably short metal-metal bonds: a lantern-type quintuply bonded dichromium(I) complex.
TLDR
The use of amidinate ligand ArNC(H)NAr (Ar= 2,6-C6H3(CH3)2) to stabilize mixed-valent Cr2 3+ complex [Cr2(ArNC( H)N Ar)3] (2) with formal Cr Cr bond order of 4.0).
Dissecting Porosity in Molecular Crystals: Influence of Geometry, Hydrogen Bonding, and [π···π] Stacking on the Solid-State Packing of Fluorinated Aromatics.
TLDR
This study examined the effects of molecular structure of the precursors on the formation of porous solid-state structures with a series of 16 rigid aromatics possessing pyrazole groups capable of hydrogen bonding and [π···π] stacking.
Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination.
Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex,
Bond characterization on a Cr-Cr quintuple bond: a combined experimental and theoretical study.
TLDR
A combined experimental and theoretical charge density study on a quintuply bonded dichromium complex, Cr(2)(dipp)(2) (dipp = (Ar)NC(H)N(Ar) and Ar = 2,6-i-Pr(2)-C(6)H(3), which confirms the existence of a quintuple bond.
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