Chew Pheng Yap

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A pentacoordinated triphosphine benzenedithiolatoiron(II) complex containing a vacant site for binding has been prepared and characterized. The complex is found to be a robust proton reduction catalyst with an overpotential of 0.56 V and a turnover frequency of 2900 s-1 with respect to 0.28 M acetic acid as the proton source. A mechanism describing the(More)
Photoluminescence data are reported for two W(CO)4L complexes (L = 2-(1H-imidazol-2-yl)pyridine and 2-(2'-pyridyl)benzimidazole) in room-temperature solutions. The bidentate ligands consist of a pyridine and an imidazole moiety connected by a C-C bond. The complexes have been found to exhibit enhanced phosphorescence from the metal-to-ligand charge transfer(More)
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