Chahrazed Beghidja

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New mononuclear [Mn(HL)3].2CHCl3 (H2L = 2-salicyloylhydrazono-1,3-dithiolane) and binuclear Mn2(mu-OCH3)2(HL)4 manganese (III) complexes have been synthesized and structurally characterized. The binuclear complex, described in this communication, displays very strong intramolecular ferromagnetic coupling (J = + 19.7 cm-1), which is confirmed by DFT(More)
The title compound, [Na(C(10)H(9.5)N(2)O(2)S(2))(2)(H(2)O)], is a mol-ecular sodium complex with N'-(1,3-dithio-lan-2-yl)-2-hy-droxy-benzohydrazide ligands with the negative charge spread evenly over both, and a water mol-ecule. The Na(I) ion coordination is distorted trigonal-bipyramidal, formed by two N and three O atoms, with the Na(I) ion lying on a(More)
Discrete and extended architectures based on the association of lanthanide ions with two derivatives of cinnamic acid (2-methoxycinnamic acid and 3-methoxycinnamic acid) have been synthesized and characterized by IR spectroscopy, elemental analyses, X-ray diffraction and magnetic measurements. The use of the 2-methoxycinnamic ligand enables the synthesis of(More)
In the title complex, [Cu(C(9)H(7)N(2)O(2)S)(2)], the Cu(II) ion, located on an inversion center, adopts an N(2)O(2) square-planar coord-ination. The 2-(5-methyl-sulfanyl-1,3,4-oxadiazol-2-yl)phenolate ligand is chelated to the central Cu(II) ion in an N,O-bidentate manner.
The title compound, [Ni(C(5)H(7)O(2))(2)(C(5)H(5)N)(2)]·2H(2)O, crystallizes with two half-mol-ecules in the asymmetric unit. The Ni(II) ion of each unique complex mol-ecule lies on an inversion centre and has an octa-hedral coordination geometry. The crystal structure features weak O-H⋯O hydrogen bonds, which form chains running parallel to the a axis.
The title compound, {[Co(C10H8N2)2(H2O)2](NO3)2·4H2O} n , (C10H8N2 = 4,4'-bipyridine = 4,4'-bpy) is a layered coordination polymer built up from a cationic square grid extending in (101) enclosing uncoordinating nitrate ions and water mol-ecules. The Co(II) ion has site symmetry 2 and one of the 4,4'-bpy ligands is generated by twofold symmetry [two N atoms(More)
In the title hydrated salt, [NiCl(C10H8N2)2](NO3)·3H2O, the Ni(2+) ion is coordinated by two 2,2'-bipyridyl (2,2'-bpy) ligands and a chloride ion in a trigonal-bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2'-bpy ring systems is 72.02 (6)°. In the crystal, the components are linked by C-H⋯O and O-H⋯O(More)
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