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Journals and Conferences
Complexes containing pyridine-2-carboxaldehyde (pyca) ligand acting as κ(2)-(N,O) chelates in [MX(CO)(3)(pyca)] (M = Mn, Re; X = Cl, Br), or [MoX(methallyl)(CO)(2)(pyca)] (X = Cl, Br), are good… (More)
New receptors fac-[Re(CO)3(pz)3]BAr'4 (pz = 3,5-dimethylpyrazole or 3(5)-tert-butylpyrazole, Ar' = 3,5-(CF3)2C6H3), synthesized from [Re(OTf)(CO)5] and the pyrazoles, have been found to show a high… (More)
Symmetric meso-tetraarylporphyrins bearing phenanthrene, pyrene, and corannulene moieties in meta positions have been synthesized in a straightforward procedure under microwave irradiation by… (More)
Condensation of two molecules of pyridine-2-carboxaldehyde (pyca), in the presence of MnCl(2) and ammonium diethyldithiophosphate, produced, in a one-pot reaction, Mn(II) complexes containing… (More)
The aldehyde function coordinated as eta(1); eta(2) is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction.
Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which… (More)
A formal direct carboboration of carbonyl ligands to form manganese boroxycarbenes in a one-pot fashion is reported.
The phosphide-bridged dimolybdenum complexes (H-DBU)[Mo2Cp2(mu-PR2)(CO)4] (R= Cy, Ph; DBU = 1,8-diazabicyclo[5.4.0.]undec-7-ene) react with p-benzoquinone to give the hemiquinone complexes… (More)
The reactions of cis-[MoCl(η(3)-methallyl)(CO)(2)(NCMe)(2)] (methallyl = CH(2)C(CH(3))CH(2)) with Na(NCNCN) and pz*H (pzH, pyrazole, or dmpzH, 3,5-dimethylpyrazole) lead to… (More)