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Nanocomposite films obtained by TiO2 incorporation into a polypropylene (PP) polymer matrix were prepared via a straightforward melting process. The structural characteristics of the nanocomposite materials were examined by a multitechnique approach showing the outstanding morphological uniformity of the films. TiO2 incorporation into the polymer matrix… (More)
A cascade silver(I)-catalyzed hydroamination/Michael addition sequence has been developed to deliver highly substituted bicyclic guanidines. This transformation gives rise to geometrically and constitutionally stable ene-guanidines and generates a remote stereocenter with moderate to high diastereoselectivity.