Cathérine Mitzenheim

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The platinum(ii) complex [Pt(H)2(dcpe)] (; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) reacts with an excess of the dialkoxymethylsilanes (HSiMe(OR)2; R = Me, Et) to give the bis(silyl) complex [Pt(SiH2Me)2(dcpe)] () and trialkoxymethylsilanes by hydrodealkoxylation reactions. These rearrangements of the silyl ligands involve Si-O bond activations. The(More)
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