Carsten Auel

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H-Li distances and (1)H-(1)H dipolar interactions in Me(2)CuLiLiCN and Me(2)CuLi in diethyl ether (Et(2)O), obtained by NMR spectroscopy, were used to gain structural information about the contact ion pair of the salt-containing organocuprate Me(2)CuLiLiCN in this solvent. The H-Li distances of Me(2)CuLiLiCN and Me(2)CuLi in Et(2)O, resulting from the(More)
The molecular sizes of higher aggregates of dimethylcuprates (Me(2)CuLi (1), 1.LiI, and 1.LiCN) and bis[(trimethylsilyl)methyl]cuprates ((Me(3)SiCH(2))(2)CuLi (2), 2.LiI, and 2.LiCN) in diethyl ether (Et(2)O) were determined by pulsed field gradient (PFG) NMR diffusion measurements. The obtained diffusion coefficients show molecular sizes larger than those(More)
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