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Recent Applications of Palladium‐Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries
In this review different examples from 2001-2008 are highlighted, which have been performed at least on a kilogram scale in the chemical and pharmaceutical industries.
Iron-catalyzed hydrogen production from formic acid.
The first light-driven iron-based catalytic system for hydrogen generation from formic acid is reported and it is shown that the reaction mechanism includes iron hydride species which are generated exclusively under irradiation with visible light.
Ligand-induced changes in the structure and dynamics of a human class Mu glutathione S-transferase.
The dynamic properties of GSTM2-2 were investigated over a wide range of time scales using (15)N nuclear spin relaxation, residual dipolar couplings, and amide hydrogen-deuterium exchange rates, showing that the majority of the protein backbone is rigid on the nanosecond to picosecond time scale for all forms of the enzyme.
Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries
Preparation and characterization of cellulose-based barrier coatings for producing a release-liner out of a porous base paper
A novel silicone release liner was prepared from porous base paper with a simple biogenic polymeric pre-coat. The introduced method does not require the typical complex pretreatment processes for a…
Practical imidazole-based phosphine ligands for selective palladium-catalyzed hydroxylation of aryl halides.
Palladium-catalyzed hydroxylation of aryl halides under ambient conditions.
A general palladium-catalyzed amination of aryl halides with ammonia.
A new robust palladium/phosphine catalyst system for the selective monoarylation of ammonia with different aryl bromides and chlorides has been developed and full conversion is achieved with most substrates with 1-2 mol % of Pd source and a fourfold excess of ligand (L).
Efficient palladium-catalyzed coupling reactions of aryl bromides and chlorides with phenols.
A convenient and general palladium-catalyzed coupling reaction of aryl bromides and chlorides with phenols was developed. Various functional groups such as nitriles, aldehydes, ketones and esters are…
Improved palladium-catalyzed Sonogashira coupling reactions of aryl chlorides.
It is undeniable that the most effective way to form aryl–alkyne bonds is still palladium-catalystzed coupling reactions of aromatic halides with alkynes in the presence of base and copper co-catalysts.