A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
- G. Férey, C. Mellot‐Draznieks, I. Margiolaki
- Materials ScienceScience
- 23 September 2005
This crystal structure for porous chromium terephthalate, MIL-101, with large poresizes and surface area has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.
A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration.
- T. Loiseau, C. Serre, G. Férey
- Materials ScienceChemistry
- 19 March 2004
Analysis of the hydration process by solid-state NMR has clearly indicated that the trapped water molecules interact with the carboxylate groups through hydrogen bonds, but do not affect the hydroxyl species bridging the aluminum atoms.
Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging.
- P. Horcajada, T. Chalati, R. Gref
- Biology, Materials ScienceNature Materials
- 1 February 2010
It is shown that specific non-toxic porous iron(III)-based metal-organic frameworks with engineered cores and surfaces, as well as imaging properties, function as superior nanocarriers for efficient controlled delivery of challenging antitumoural and retroviral drugs against cancer and AIDS.
Metal-organic frameworks in biomedicine.
- P. Horcajada, R. Gref, C. Serre
- HistoryChemical Reviews
- 8 February 2012
Metal Organic Frameworks in Biomedicine Patricia Horcajada,* Ruxandra Gref, Tarek Baati, Phoebe K. Allan, Guillaume Maurin, Patrick Couvreur, G erard F erey, Russell E. Morris, and Christian Serre*…
Synthesis and catalytic properties of MIL-100(Fe), an iron(III) carboxylate with large pores.
- P. Horcajada, S. Surblé, G. Férey
- ChemistryChemical Communications
- 4 July 2007
The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data,…
Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47.
- S. Bourrelly, P. Llewellyn, C. Serre, F. Millange, T. Loiseau, G. Férey
- Materials ScienceJournal of the American Chemical Society
- 13 September 2005
A distinct step in the isotherm occurs during the adsorption of CO2 on MIL-53 at 304 K and it is suggested that a breathing behavior is induced in MIL- 53 during CO2 adsorptive activity.
High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101.
- P. Llewellyn, S. Bourrelly, G. Férey
- Materials ScienceLangmuir
- 21 March 2008
Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gas-solid interactions in Mesoporous MOFs MIL-100 and MIL-101.
Hydrogen storage in the giant-pore metal-organic frameworks MIL-100 and MIL-101.
- M. Latroche, S. Surblé, G. Férey
- Chemistry, MedicineAngewandte Chemie
- 11 December 2006
Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy
- C. Serre, F. Millange, G. Férey
- Materials Science, Chemistry
- 19 October 2002
The first three-dimensional chromium(III) dicarboxylate, MIL-53as or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}0.75, has been obtained under hydrothermal conditions (as: as-synthesized). The free acid…
A new photoactive crystalline highly porous titanium(IV) dicarboxylate.
- M. Dan-Hardi, C. Serre, G. Férey
- Materials ScienceJournal of the American Chemical Society
- 21 July 2009
MIL-125, the first example of a highly porous and crystalline titanium(IV) dicarboxylate with a high thermal stability and photochemical properties, is presented, a very promising candidate for applications in smart photonic devices, sensors, and catalysis.
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