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Multivalency as a chemical organization and action principle.
In a systematic review of scaffold architectures, the underlying effects and control options will be demonstrated, and suggestions will be given for designing effective multivalent binding systems, as well as for polyvalent therapeutics. Expand
Analytical methods in supramolecular chemistry
Preface Volume One INTRODUCTION Some Historical Remarks on Supramolecular Chemistry The Noncovalent Bond: a Brief Overview Basic Concepts in Supramolecular Chemistry Conclusions: Diverse Methods forExpand
The expanding role of mass spectrometry in biotechnology Gary Siuzdak
Comparable to the exciting development of nuclear magnetic resonance methods during the past three decades, mass spectrometry entered a phase of quick growth in the mid-eighties beginning with theExpand
Enzyme-responsive pillar[5]arene-based polymer-substituted amphiphiles: synthesis, self-assembly in water, and application in controlled drug release.
An enzyme-responsive drug delivery system was constructed from a pillar[5]arene-based polyethyleneglycol-substituted amphiphile which self-assembles into micelles in water. These micelles exhibitExpand
Experimental evidence for the functional relevance of anion-pi interactions.
It is concluded that anion-pi interactions on monomeric surfaces are ideal for chloride recognition, whereas their supramolecular enhancement by pi,pi-interactions appears perfect to target nitrate. Expand
Investigating Molecular Recognition by Mass Spectrometry: Characterization of Calixarene-Based Self-Assembling Capsule Hosts with Charged Guests
Capsules derived from the reversible assembly of calixarene tetraureas have been characterized by electrospray ionization mass spectrometry. Ion labeling was achieved through the encapsulation ofExpand
Rotaxane or Pseudorotaxane? Effects of Small Structural Variations on the Deslipping Kinetics of Rotaxanes with Stopper Groups of Intermediate Size
Three series of rotaxanes have been synthesized variously by slipping synthesis, in which axis and wheel are melted in admixture, by recognition of amide groups inside the macrocyclic wheel, or by anExpand
Supramolecular polymers as surface coatings: rapid fabrication of healable superhydrophobic and slippery surfaces.
The self-assembly of low-molecular-weight gelators with perfluorinated side chains can be utilized to rapidly construct superhydrophobic, as well as liquid-infused slippery surfaces within minutes. Expand
Halogen-Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase.
The stability of the XB capsules in the gas phase was confirmed by electrospray ionization mass spectrometry (ESI-MS), and a new guest binding site was uncovered within the elongated iodoethynyl capsule. Expand