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Nonequilibrium Equality for Free Energy Differences
- C. Jarzynski
- Physics
- 30 October 1996
An expression is derived for the equilibrium free energy difference between two configurations of a system, in terms of an ensemble of finite-time measurements of the work performed in parametrically…
Equilibrium free-energy differences from nonequilibrium measurements: A master-equation approach
- C. Jarzynski
- Physics
- 30 July 1997
It has recently been shown that the Helmholtz free energy difference between two equilibrium configurations of a system may be obtained from an ensemble of finite-time (nonequilibrium) measurements…
Equalities and Inequalities: Irreversibility and the Second Law of Thermodynamics at the Nanoscale
- C. Jarzynski
- Physics
- 8 February 2011
The reason we never observe violations of the second law of thermodynamics is in part a matter of statistics: When ∼1023 degrees of freedom are involved, the odds are overwhelmingly stacked against…
Verification of the Crooks fluctuation theorem and recovery of RNA folding free energies
- D. Collin, F. Ritort, C. Jarzynski, S. Smith, I. Tinoco, C. Bustamante
- BiologyNature
- 8 September 2005
TLDR
Classical and quantum fluctuation theorems for heat exchange.
- C. Jarzynski, D. Wójcik
- PhysicsPhysical review letters
- 20 April 2004
The statistics of heat exchange between two classical or quantum finite systems initially prepared at different temperatures are shown to obey a fluctuation theorem.
Good practices in free-energy calculations.
- A. Pohorille, C. Jarzynski, C. Chipot
- EngineeringThe journal of physical chemistry. B
- 22 July 2010
TLDR
Hamiltonian Derivation of a Detailed Fluctuation Theorem
- C. Jarzynski
- Physics
- 19 August 1999
We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive…
Stochastic and Macroscopic Thermodynamics of Strongly Coupled Systems
- C. Jarzynski
- Physics
- 24 January 2017
Thermodynamics describes how macroscopic systems exchange energy in the form of heat and work, yet many microscopic systems such as molecular motors exhibit behavior that seems to follow the same…
Rare events and the convergence of exponentially averaged work values.
- C. Jarzynski
- PhysicsPhysical review. E, Statistical, nonlinear, and…
- 7 March 2006
TLDR
Comparison of far-from-equilibrium work relations
- C. Jarzynski
- Physics
- 12 December 2006
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