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Catalytic formation of acrylate from carbon dioxide and ethene.
TLDR
It is shown that the catalytic conversion of ethene and CO2 to acrylate is possible in the presence of a homogeneous nickel catalyst in combination with a "hard" Lewis acid and for the first time, catalytic conversions with turnover numbers (TON) of up to 21 was demonstrated. Expand
Rhodium-mediated stereoselective polymerization of "carbenes".
Unprecedented rhodium-catalyzed stereoselective polymerization of "carbenes" from ethyl diazoacetate (EDA) to give high molecular mass poly(ethyl 2-ylidene-acetate) is described. The mononuclear,Expand
C1-Symmetric Si-bridged (2-indenyl)(1-indenyl) ansa-metallocenes as efficient ethene/1-hexene copolymerization catalysts.
TLDR
It is shown that metallocenes bearing a 2-indenyl substituent pattern yields competent linear low-density polyethylene (LLDPE) catalysts, and that steric factors likely contribute stronger than electronic factors to the observed substituents trends, both for comonomer affinity and MW capability. Expand
CCDC 604831: Experimental Crystal Structure Determination
Related Article: D.G.H.Hetterscheid, C.Hendriksen, W.I.Dzik, J.M.M.Smits, E.R.H.van Eck, A.E.Rowan, V.Busico, M.Vacatello, V.Van A.Castelli, A.Segre, E.Jellema, T.G.Bloemberg, B.deExpand
CCDC 604834: Experimental Crystal Structure Determination
Related Article: D.G.H.Hetterscheid, C.Hendriksen, W.I.Dzik, J.M.M.Smits, E.R.H.van Eck, A.E.Rowan, V.Busico, M.Vacatello, V.Van A.Castelli, A.Segre, E.Jellema, T.G.Bloemberg, B.deExpand
Synthesis of alpha, beta-unsaturated carboxylic acids, (meth) acrylates of olefins
Gegenstand der vorliegenden Erfindung ist ein Verfahren zur Herstellung zur Herstellung von α,β-ungesattigten Carbonsauren oder deren Salze, durch Umsetzung eines Olefins, welches 2 oder 3Expand
CCDC 604832: Experimental Crystal Structure Determination
Related Article: D.G.H.Hetterscheid, C.Hendriksen, W.I.Dzik, J.M.M.Smits, E.R.H.van Eck, A.E.Rowan, V.Busico, M.Vacatello, V.Van A.Castelli, A.Segre, E.Jellema, T.G.Bloemberg, B.deExpand
Synthesis of a, ß-unsaturated carboxylic acids, (meth) acrylates of olefins and CO2
The present invention is a process for the preparation of α, β-unsaturated carboxylic acids or salts thereof, which comprises a step in which a complex is reacted in a solvent in the presence of aExpand
Alkoxide packaged sodium dihydrogenphosphide: synthesis and reactivity
This work aims to describe the activation of white phosphorus to form highly functionalized compounds. White phosphorus is used as starting material as it is a highly reactive and selective reagent.Expand
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