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This chapter discusses a cluster of insulin mediator peptides that duplicate in vitro the following insulin actions in the cell: (1) inhibit cyclic adenosine monophosphate (cAMP)dependent protein… (More)
Abstract Many para-substituted fluorobenzenes can be lithiated ortho to fluorine in moderate to good yields, often with one of the dialkylamide bases, lithium diisopropylamide (LDA) or lithium… (More)
We describe a new tandem radical cyclization strategy for the construction of the congested angular triquinane portion of the naturally occurring tetraquinane crinipellin A. The preparation and… (More)
SummaryBrief treatment of rat adipocytes with low concentration of trypsin activated both cell membrane and intracellular insulin-sensitive functions in marked contrast to H2O2 (1), increase in pH,… (More)
Abstract A simple 2-step synthesis of B-ring substituted benzo[b]thiophene-2-carboxylates from aryl fluorides has been developed. The route involves a selective lithiation ortho to fluorine, followed… (More)