Sorry, we do not have enough data to show an influence graph for this author.
- Full text PDF available (0)
- This year (0)
- Last 5 years (0)
- Last 10 years (0)
Journals and Conferences
[reaction: see text] The readily available N-(O-ethyl thiocarbonylsulfanyl)amides are powerful amidyl radical precursors that undergo 5-exo cyclization to give pyrrolidinone derivatives via a radical-chain reaction initiated by a small amount of lauroyl peroxide.
Amidyl radicals are readily generated from N-allylsulfonimides by the action of a xanthate and a small amount of a peroxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond; in some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap.