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As early as the 17th century it was recognized that one component in air is essential for life. This extremely simple molecule later known as dioxygen or commonly oxygen was discovered by Joseph… (More)
Intermediates of the catalytic cycles of chloroperoxidase and cytochrome P450cam are identified and characterized by means of synthetic enzyme models.
Photoassociation of metastable He (2/sup 3/S/sub 1/) atoms at ultra low temperatures close to the BEC phase transition is studied, which was achieved previously in an Ioffe-Pritchard magnetic trap… (More)
The heme-thiolate protein chloroperoxidase (CPO) catalyzes the chlorination of activated CH bonds. A reaction mechanism is proposed for this enzymatic transformation (Scheme 1), and a new iron(III)… (More)