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Journals and Conferences
The positively charged layered gadolinium hydroxide nanosheets were produced by exfoliation in formamide and was applied to fabricate highly transparent and highly luminescent Gd(2)O(3) : Eu layers on quartz glass by simple evaporation and subsequent annealing.
In the process of optimization, we developed a novel core skeleton of thieno[3,4-b]pyrazine via GK-13. The derivatives synthesized were shown to inhibit TGase 2 activity in cancer cells. Some of the hit compounds such as the arylethynyl group-coupled thieno[3,4-b]pyrazine derivatives were shown to exhibit promising activity for use as potential therapeutic… (More)
La(OH)(3) nanorods were self-stacked on the glass slide substrates using an aqueous suspension obtained from the hydrolysis of LaOCl. The key for producing a high optical quality film of La(OH)(3) lies in the preparation of an aqueous suspension in which La(OH)(3) nanorods are well dispersed. These thin-film coatings of La(OH)(3) nanorods led to a… (More)
A layered gadolinium hydroxychloride (LGdH), [Gd2(OH)5(H2O)x]Cl, was synthesized from an aqueous solution of GdCl3.6H2O. The X-ray diffraction (XRD) and the selected area electron diffraction (SAED) studies showed that this compound crystallizes in the orthorhombic structure (a = 12.88(4) A, b = 7.30(2) A, and c = 8.46(3) A) which is isostructural with… (More)
A new composite film based on calcined layered rare earth hydroxides and poly(vinyl alcohol) shows a visible light transmittance comparable to that of the pure matrix, highly reinforced mechanical strength as well as tunable photoluminescence in rolled and folded shapes.
Simply mixing layered rare-earth hydroxide colloidal solutions and paratungstate solution at pH > 7 led to directional self-assembly of rare-earth hydroxide nanosheets and paradodecatungstates. These hybrids exhibit efficient energy transfer from the OMCT band to rare-earth ions in the hydroxide layers as well as highly enhanced f-f transitions.
Construction of a rose-like hierarchical superstructure composed of rare-earth hydroxide nanosheets and polyoxomolybdates, which was achieved by the self-assembly at room temperature, led to a drastically enhanced photoluminescence.
A simple way to detect and remove trace amounts of WO4(2-) ions from an aqueous solution was demonstrated by their light-harvesting ability and selective excitation energy transfer to a Tb-doped layered yttrium hydroxynitrate matrix.
The excitation of the adsorbed vanadate group led to the red emission arising from the efficient energy transfer to Eu-doped layered gadolinium hydroxide (LGdH:Eu). This light-harvesting antenna effect allowed LGdH:Eu to detect selectively a vanadate in aqueous solution at different pHs. Because vanadate exists in various forms by extensive oligomerization… (More)
Phase studies were undertaken with PbFCl-type rare earth oxychlorides (REOCls), where RE = La-Dy and Y. Specifically, equilibria in REOCl-H2O systems were investigated in an effort to describe the interrelationship of the oxychloride, hydroxychloride, and trihydroxide phases of rare earths in water. When lighter rare earths were employed, REOCls were… (More)