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Remodeling of the Natural Product Fumagillol Employing a Reaction Discovery Approach
- Bradley R. Balthaser, Meghan Maloney, A. Beeler, J. Porco, J. K. Snyder
- Chemistry, Medicine
- Nature Chemistry
- 11 October 2011
In the search for new biologically active molecules, diversity-oriented synthetic strategies break through the limitation of traditional library synthesis by sampling new chemical space. Many natural… Expand
Brønsted acid-promoted glycosylations of disaccharide glycal substructures of the saccharomicins.
An acid-promoted glycosylation and alkynol cycloisomerization sequence provided direct access to the 2-deoxytrisaccharide corresponding to the fucose-saccharosamine-digitoxose substructure of… Expand