Bradley Cowie

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Reaction of [PtCl(2)(COD)] and [PtI(2)(COD)] with 2,7-di-tert-butyl-5-diphenylboryl-4-diphenylphosphino-9,9-dimethylthioxanthene (TXPB) afforded square planar [PtCl(2)(TXPB)] (1B) and [PtI(2)(TXPB)] (4B), both of which were crystallographically characterized. Single-crystal X-ray quality crystals were also obtained for [PdCl(2)(TXPB)] (2B; Emslie et al.,(More)
An aryldimethylalane-appended analogue of 1,1'-bis(diphenylphosphino)ferrocene, FcPPAl, was prepared, and reaction with [Pt(nb)3 ] (nb=norbornene) afforded [Pt(η(2) -nb)(FcPPAl)] (1). Heating a solution of 1 to 80 °C resulted in crystallization of [{Pt(FcPPAl)}2 ] (2), whereas treatment of 1 with C2 H4 , C2 Ph2 , H2 , or CO provided [PtL(FcPPAl)] [L=C2 H4(More)
This paper considers the complexities involved in obtaining training data for use by artificial intelligence constructs to identify potential network incidents using passive network telescope data. While a large amount of data obtained from network telescopes exists, this data is not currently marked for known incidents. Problems related to this marking(More)
A bis(phosphine)borane ambiphilic ligand, [Fe(η(5) -C5 H4 PPh2 )(η(5) -C5 H4 PtBu{C6 H4 (BPh2 )-ortho})] (FcPPB), in which the borane occupies a terminal position, was prepared. Reaction of FcPPB with tris(norbornene)platinum(0) provided [Pt(FcPPB)] (1) in which the arylborane is η(3) BCC-coordinated. Subsequent reaction with CO and CNXyl(More)
The eld of Information Security and the subeld of cryptographic protocols are both vast and continually evolving and expanding elds. The use of cryptographic protocols as a means to provide security to web servers and services at the transport layer, by providing both encryption and authentication to data transfer, has become increasingly popular. I intend(More)
Cyclic boron-containing π-ligands such as boratabenzenes and borollides are well established, in particular as supporting ligands. By contrast, the chemistry of acyclic boron-containing π-ligands has remained relatively unexplored, presumably in part due to the higher reactivity of acyclic π-ligands relative to cyclic analogues. This perspective is focused(More)
1 INTRODUCTION This paper describes research in the eld of cryptographic protocols, currently being performed in the REMOVED. While this research is not entirely novel, as it makes use of elements from existing research in the detection of encrypted applications [2], we consider a generic solution to the given problem of analysing encrypted trac with the(More)
The reduction of UVI uranyl halides or amides by simple LnII or UIII salts forms highly symmetrical, linear, oxo-bridged trinuclear UV-LnIII-UV, LnIII-UIV-LnIII and UIV-UIV-UIV complexes or linear LnIII-UV polymers according to the stoichiometry and solvent choice. Reactions can be tuned to give one- or two-electron uranyl reduction. Some features of their(More)
Reaction of the neutral ambiphilic ligand 2,7-di-tert-butyl-5-diphenylboryl-4-diphenylphosphino-9,9-dimethylthioxanthene (TXPB) with [{Rh(mu-Cl)(CO)(2)}(2)] yields [RhCl(CO)(TXPB)] (1) (Emslie et al. Organometallics 2006, 25, 5835). Complex 1 is square planar with the TXPB ligand bound to rhodium via the phosphine and thioether donors (these are features(More)
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