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Naming reactions after their discoverers has a long tradition. This tradition is more prevalent in organic chemistry than in any other branch of chemistry. By this tradition, the chemical world not… (More)
A 13C nmr analysis method is described for the identification of carbohydrate residues in galactosides and glucosides. This method reveals the capability of 13C nmr to distinguish the difference in...
Reevaluation of the previously proposed structure of helminthosporoside, a host-specific toxin fromHelminthosporium sacchari, reveals a sesquiterpenoid bis-digalactoside. The carbohydrate portion of… (More)
Abstract A concise and isotope specific synthesis of deuterated analogs of 4-hydroxyalkenals is reported.
Abstract A stereospecific synthesis of 2-isopropylidene- cis,cis -4,8-dimethyl-6-keto- cis -decahydroazulene ( 3 ) has been accomplished. Each of the 19 synthetic steps proceeds in good to excellent… (More)