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Synthesis and antiviral activities of phenanthroindolizidine alkaloids and their derivatives.
- Kailiang Wang, Bo Su, Qingmin Wang
- Chemistry, BiologyJournal of agricultural and food chemistry
- 10 March 2010
These findings demonstrate that these phenanthroindolizidine alkaloids and their salt derivatives represent a new template for antiviral studies and could be considered for novel therapy against plant virus infection.
A Simple and Efficient Oxidative Coupling of Aromatic Nuclei Mediated by Manganese Dioxide
Oxidative intramolecular coupling of the aryl rings of various stilbenes for direct construction of the phenanthrene ring system is promoted efficiently by manganese dioxide―trifluoroacetic acid at…
Bioinspired construction of a spirocyclohexadienone moiety via sodium nitrite catalyzed aerobic intramolecular oxidative phenol coupling.
An efficient and green intramolecular oxidative phenol coupling for the direct construction of spirocyclohexadienones has been developed, which uses environment-friendly sodium nitrite as the…
Sodium Nitrite-Catalyzed Aerobic Oxidative Csp2Csp3 Coupling: Direct Construction of the 4-Aryldihydroisoquinolinone Moiety
An enantioselective strategy for the synthesis of (S)-tylophorine via one-pot intramolecular Schmidt/Bischler-Napieralski/imine-reduction cascade sequence.
A novel enantioselective strategy for the total synthesis of (S)-tylophorine was developed in an overall yield of 48% with more than 99% ee from readily avaliable azido acid and phenanthryl alcohol.…
A Novel Sodium Nitrite-Catalyzed Oxidative Coupling for Constructing Polymethoxyphenanthrene Rings
An efficient and green oxidative coupling for the direct construction of polymethoxyphenanthrene rings has been developed, which uses environment-friendly sodium nitrite as catalyst and oxygen as…
Design, synthesis, antiviral activity, and SARs of 13a-substituted phenanthroindolizidine alkaloid derivatives.
m-CPBA/TFA: an efficient nonmetallic reagent for oxidative coupling of 1,2-diarylethylenes
Design, synthesis, antiviral activity, and structure-activity relationships (SARs) of two types of structurally novel phenanthroindo/quinolizidine analogues.
- Bo Su, F. Chen, Lizhong Wang, Qingmin Wang
- ChemistryJournal of agricultural and food chemistry
- 3 February 2014
To investigate the influence of the variation of the original skeletons of natural phenanthroindo/quinolizidine alkaloids on antiviral activities, two types of structurally totally novel analogues…
An enantioselective strategy for the total synthesis of (S)-tylophorine via catalytic asymmetric allylation and a one-pot DMAP-promoted isocyanate formation/Lewis acid catalyzed cyclization sequence.
A new asymmetric total synthesis of a phenanthroindolizidine alkaloid (S)-tylophorine is reported, which features a catalytic asymmetric allylation of aldehydes and an unexpected one-pot DMAP…