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Bifurcate hydrogen bonds. Interaction of intramolecularly H-bonded systems with Lewis bases.
The structure and the hydrogen bonding in the systems formed by the intramolecularly H-bonded systems, namely, maltol (3-hydroxy-2-methyl-4-pyrone), 5, 2,4,6-trinitrophenol, 6, acetylacetone enol, 7,Expand
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Diamines Having a C2 Symmetry. Synthesis and Application as Ligands in the Hydrogenation of Prochiral Substrates over Rhodium Complexes
Chiral diamines having a C2 symmetry, (4S,5S)-2,2-dimethyl-4,5-bis(aminomethyl)-1,3-dioxolane and (5S,5'S)-2,2,2',2'-tetramethyl-3,3'-diphenyl-5,5'-bioxazolidine, were synthesized on the basis ofExpand
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Electrochemical Fluorination of Benzamide and Acetanilide in Anhydrous HF and in Acetonitrile
Electrochemical fluorination of benzamide in anhydrous hydrogen fluoride does not involve the amide group but occurs exclusively at the aromatic ring, yielding isomeric fluoro- and difluorobenzamidesExpand
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Intramolecular hydrogen bonds in the sulfonamide derivatives of oxamide, dithiooxamide, and biuret. FT-IR and DFT study, AIM and NBO analysis
Abstract The hydrogen bonding in [(1-arylsulfonylamino-2,2,2-trichloro)ethyl]biuret 1, [(1-arylsulfonylamino-2,2,2-trichloro)ethyl]oxamide 2, andExpand
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Trifluoromethanesulfonamides and related compounds.
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Conformational preferences of Si–Ph,H and Si–Ph,Me silacyclohexanes and 1,3-thiasilacyclohexanes. Additivity of conformational energies in 1,1-disubstituted heterocyclohexanes
Abstract The conformational equilibria of 1-phenyl-1-silacyclohexane 1, 3-phenyl-1,3-thiasilacyclohexane 2, 1-methyl-1-phenyl-1-silacyclohexane 3, and 3-methyl-3-phenyl-1,3-thiasilacyclohexane 4 haveExpand
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Silacyclohexanes and silaheterocyclohexanes—why are they so different from other heterocyclohexanes?
Stereochemical studies on silaheterocyclohexanes is a ‘hot topic’ as evidenced by the growing number of publications. During last 10 years a substantial number of substituted silacyclohexanes andExpand
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The Carbon?Nitrogen Triad Prototropic Tautomerism
Data on the imine–enamine and related types of tautomerism are surveyed and different approaches to problems of the tautomerism of enamides, which play a major role in biological processes, areExpand
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Conformational analysis of 3‐methyl‐3‐silathiane and 3‐fluoro‐3‐methyl‐3‐silathiane
The conformational equilibria of 3-methyl-3-silathiane 5, 3-fluoro-3-methyl-3-silathiane 6 and 1-fluoro-1-methyl-1- silacyclohexane 7 have been studied using low temperature C-13 NMR spectroscopy andExpand
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