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Photolysis of arene chromium tricarbonyl complexes in presence of amine–boranes: Observation of σ-borane complexes in solution
Activation of the B-H sigma-bond of amine-boranes on the chromium(0) center of arene chromium tricarbonyl complexes (eta(6)-arene) Cr(CO)(3) (arene = fluorobenzene, 1a; benzene, 1b and mesitylene,Expand
Spectrophotometric determination of selenium with 2-mercaptobenzothiazole
A rapid, sensitive and selective spectrophotometric method has been developed for the determination of micro amounts of selenium. This method is based on the absorptiometric measurement of the stableExpand
A homobimetallic complex of chromium(0) with a σ-borane component.
The synthesis, characterization, and reactivity of a chromium(0) complex bearing an amine-borane moiety (η(6)-C(6)H(5)CH(2)NMe(2)·BH(3))Cr(CO)(3) (2) is reported. Photolysis of complex 2 results inExpand
Spectrophotometric determination of osmium with 2-mercaptobenzothiazole
Abstract A new spectrophotometric method for osmium is described which is based on the extraction of the blue precipitate formed by the reaction with 2-Mercaptobenzothiazole at pH ~ 4, andExpand
Amperometric titration of mercury with a stationary platinum electrode in stirred solutions.
Amperometric titration of mercury (in the range of 0-4 to 3.5 mg) has been carried out with 2-mercaptobenzoxazole with a stationary electrode in stirred solution in a sodium acetate-acetic acidExpand
Dynamics of H-atom exchange in stable cis-dihydrogen/hydride complexes of ruthenium(II) bearing phosphine and N-N bidentate ligands.
Synthesis and characterization of cis,trans-[RuH(η(2)-H2)(PPh3)2(N-N)][OTf] (N-N = 2,2'-bipyridyl (bpy) 1a, 2,2'-bipyrimidine (bpm) 2a; OTf = trifluoromethane sulfonate (CF3SO3)) complexes areExpand
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