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A facile synthesis of α-chloroboronic esters via the base induced reaction of α,α-dichloromethyl methyl ether with hindered borinic esters
Abstract Treatment of hindered borinic esters, R2 BOR′; with an equimolar quantity of α,α-dichloromethyl methyl ether and lithium triethylcarboxide yields the α-chloroboronic esters, R2Expand
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Polyester chain scission by selective chemical site attack
Tribenzylamine moieties copolymerized into poly(ethylene terephthalate) (PET) are selectively cleaved by mild hypochlorous acid oxidation to give dibenzylamines plus aldehyde and/or carboxyl groups.Expand