Atash V. Gurbanov

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The title compound, C21H18N2O4, obtained as a racemate, contains a novel heterocyclic system, viz. isoindolo[1,2-c]pyrrolo-[1,2-a][1,4]benzodiazepine. The central diazepane ring has a distorted boat conformation with two phenyl-ene-fused and one methine C atom deviating by 0.931 (1), 0.887 (1) and 0.561 (1) Å, respectively, from the mean plane of the rest(More)
The title compound, [Fe(C7H9N2)2], crystallizes with two crystallographically independent mol-ecules in the unit cell. These represent the chiral atropoisomers distinguished by the mutual arrangement of the two acet-yl-hydrazone groups with a cis conformation of the C=N bonds. The two cyclo-penta-dienyl (Cp) rings are planar and nearly parallel, the tilt(More)
In the title compound, C21H24BrNO4, the dihedral angle between the heterocyclic ring and the pendant aromatic ring is 80.20 (13)°. The hexahydroquinone [i.e. the one with the C=O group] ring adopts a sofa conformation. An intra-molecular O-H⋯O hydrogen bond generates an S(6) ring motif. The ethyl group is disordered over two sets of sites with a refined(More)
In the title compound, [Ni(C8H14N6S2)], the Ni(II) ion is coordinated by N2S2 donor atoms of the tetradentate thio-semicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related mol-ecules are linked via pairs of N-H⋯N and N-H⋯S hydrogen bonds, forming R 2 (2)(8) ring motifs. Mol-ecules are further linked by(More)
In the title compound, C(21)H(25)NO(3), the hydro-pyridine ring that constitutes a part of the hexa-hydro-quinoline fused-ring system adopts a sofa conformation; the methine C atom deviates from the least-squares plane defined by the remaining five non-H atoms (r.m.s. deviation = 0.088 Å) by 0.454 (3) Å. The phenyl ring is aligned at 85.5 (1)° with respect(More)
The Cu(II) atom in the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(H(2)O)](n), lies in a square plane defined by the O atoms of the carboxyl-ate ions, the N atom of the N-heterocycle and the water mol-ecule. Coordination by an amido O atom of an adjacent N-heterocycle in the apical direction leads to a polymeric chain running along(More)
In the title compound, [Cu(C(12)H(11)N(2)O(4))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Cu(II) atom lies on a center of inversion and is coordinated by carboxyl-ate O atoms, pyridine N atoms and two water mol-ecules in an elongated octa-hedral geometry. The pyridine ring is oriented at a dihedral angle of 74.83 (12)° with respect to the benzene ring.(More)
In the title compound, C(16)H(25)NO, the N-tert-butyl-propanamide fragment is essentially planar, with the exception of two C atoms of the tert-butyl group (r.m.s. deviation = 0.005 Å), forming a dihedral angle of 84.09 (10)° with the plane of the mesityl fragment (r.m.s. deviation = 0.002 Å). The crystal packing is stabilized by an inter-molecular N-H⋯O(More)
The C=C bond in the title compound, C(14)H(15)NO(4), is in an E configuration. With the exception of the methyl C atoms, the non-H atoms of the mol-ecule all lie approximately on a plane (r.m.s. deviation = 0.096 Å). π-π stacking is observed between parallel benzene rings of adjacent mol-ecules, the centroid-centroid distance being 3.7924 (8) Å.