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Palladium(II)-catalyzed coupling reactions with a chelating vinyl ether and arylboronic acids: a new Heck/Suzuki domino diarylation reaction.
A mild and novel palladium(II)-catalyzed domino Heck/Suzuki alpha,beta-diarylation-reduction of a dimethylaminoethyl substituted chelating vinyl ether was developed by using electron-rich arylboronicExpand
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Evaluation of a Nonresonant Microwave Applicator for Continuous-Flow Chemistry Applications
The concept of a nonresonant microwave applicator for continuous-flow organic chemistry is introduced and evaluated. The frequency of the incident microwave radiation can be adjusted between 2.4 andExpand
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Chelation-mediated palladium(II)-catalyzed domino Heck-Mizoroki/Suzuki-Miyaura reactions using arylboronic acids: increasing scope and mechanistic understanding.
A palladium(II)-catalyzed Heck-Mizoroki/Suzuki-Miyaura domino reaction involving metal coordinating dimethylaminoethyl vinyl ethers and a number of electron-rich and electron-deficient arylboronicExpand
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Palladium(II)‐Catalyzed Decarboxylative Heck Arylations of Acyclic Electron‐Rich Olefins with Internal Selectivity
Despite the recent emergence of decarboxylative CC bond forming reactions, methodologies providing internally arylated electron-rich olefins are still lacking. We herein report on palladium(II)-catExpand
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Convenient Stille carbonylative cross-couplings using molybdenum hexacarbonyl
Abstract Palladium catalysis was used in Stille-type carbonylative cross-couplings employing Mo(CO) 6 as the carbon monoxide source. Robust and convenient transformations were carried out in closedExpand
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Chelation-Mediated Palladium(II)-Catalyzed Domino Heck—Mizoroki/Suzuki—Miyaura Reactions Using Arylboronic Acids: Increasing Scope and Mechanistic Understanding.
The treatment of vinyl ethers (I) and (IV) with various arylboronic acids and vinylboronic acid (IIj) in the presence of benzoquinone allows formation of a number of 1,2-difunctionalized ethers.
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Palladium(II)-Catalyzed Heck Reactions : Domino Reactions, Decarboxylations, Mechanistic Studies a Continuous Flow Applications
This thesis describes research efforts dedicated to the development of palladium(II)-catalyzed oxidative Heck and Heck/Suzuki domino reactions, and the applications of a new microwave heating technExpand