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Palladium(II)-catalyzed coupling reactions with a chelating vinyl ether and arylboronic acids: a new Heck/Suzuki domino diarylation reaction.
- Alejandro Trejos, Ashkan Fardost, Samir Yahiaoui, M. Larhed
- Chemistry, Medicine
- Chemical communications
- 30 November 2009
A mild and novel palladium(II)-catalyzed domino Heck/Suzuki alpha,beta-diarylation-reduction of a dimethylaminoethyl substituted chelating vinyl ether was developed by using electron-rich arylboronic… Expand
Evaluation of a Nonresonant Microwave Applicator for Continuous-Flow Chemistry Applications
- Per Öhrngren, Ashkan Fardost, F. Russo, Jon-Sverre Schanche, Magnus Fagrell, M. Larhed
- 9 March 2012
The concept of a nonresonant microwave applicator for continuous-flow organic chemistry is introduced and evaluated. The frequency of the incident microwave radiation can be adjusted between 2.4 and… Expand
Chelation-mediated palladium(II)-catalyzed domino Heck-Mizoroki/Suzuki-Miyaura reactions using arylboronic acids: increasing scope and mechanistic understanding.
- Samir Yahiaoui, Ashkan Fardost, Alejandro Trejos, M. Larhed
- Chemistry, Medicine
- The Journal of organic chemistry
- 21 March 2011
A palladium(II)-catalyzed Heck-Mizoroki/Suzuki-Miyaura domino reaction involving metal coordinating dimethylaminoethyl vinyl ethers and a number of electron-rich and electron-deficient arylboronic… Expand
Palladium(II)‐Catalyzed Decarboxylative Heck Arylations of Acyclic Electron‐Rich Olefins with Internal Selectivity
Despite the recent emergence of decarboxylative CC bond forming reactions, methodologies providing internally arylated electron-rich olefins are still lacking. We herein report on palladium(II)-cat… Expand
Convenient Stille carbonylative cross-couplings using molybdenum hexacarbonyl
Abstract Palladium catalysis was used in Stille-type carbonylative cross-couplings employing Mo(CO) 6 as the carbon monoxide source. Robust and convenient transformations were carried out in closed… Expand
Chelation-Mediated Palladium(II)-Catalyzed Domino Heck—Mizoroki/Suzuki—Miyaura Reactions Using Arylboronic Acids: Increasing Scope and Mechanistic Understanding.
The treatment of vinyl ethers (I) and (IV) with various arylboronic acids and vinylboronic acid (IIj) in the presence of benzoquinone allows formation of a number of 1,2-difunctionalized ethers.
Palladium(II)-Catalyzed Coupling Reactions with a Chelating Vinyl Ether and Arylboronic Acids: A New Heck/Suzuki Domino Diarylation Reaction.
Palladium(II)-Catalyzed Heck Reactions : Domino Reactions, Decarboxylations, Mechanistic Studies a Continuous Flow Applications
- Ashkan Fardost
This thesis describes research efforts dedicated to the development of palladium(II)-catalyzed oxidative Heck and Heck/Suzuki domino reactions, and the applications of a new microwave heating techn… Expand
Palladium(II)-Catalyzed Decarboxylative Heck Arylations of Acyclic Electron-Rich Olefins with Internal Selectivity.