Arkadiusz Listkowski

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Double hydrogen transfer occurring in both ground and the lowest electronically excited singlet states was studied for a series of 19 differently substituted porphycenes. The rates of tautomerization have been determined using femtosecond pump-probe spectroscopy with polarized light. The values vary by over 3 orders of magnitude, suggesting the importance(More)
We describe various experimental approaches that have been used to obtain a detailed understanding of double hydrogen transfer in porphycene, a model system for intramolecular hydrogen bonding and tautomerism. The emerging picture is that of a multidimensional tautomerization coordinate, with several vibrational modes acting as reaction-promoters or(More)
Investigation of the double hydrogen transfer in porphycene, its 2,7,12,17-tetra-tert-butyl derivative, and their N-deuterated isotopologues revealed the dominant role of tunneling, even at room temperature in condensed phase. Ultrafast optical spectroscopy with polarized light employed in a wide range of temperatures allowed the identification and(More)
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