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The kinetics of the high-temperature (1070-1134 K), low and high-pressure gas-phase forward water-gas shift reaction were evaluated in an empty quartz reactor and a quartz reactor packed with quartz particles. The power law expression for the reaction rate was consistent with the Bradford mechanism and was invariant with respect to pressure. The(More)
The permeance of Pd–Cu alloys containing 40, 53, 60, and 80 wt.% Pd has been determined over the 623–1173 K temperature range for H 2 partial pressure differences as great as 2.6 MPa. Pure palladium and copper membranes were also evaluated. The Pd–Cu alloys exhibited predictable permeances that reflected the crystalline phase structures as shown in the(More)
The hydrogen permeance of several 0.1 mm thick Pd–Cu alloy foils (80 wt.% Pd–20 wt.% Cu, 60 wt.% Pd–40 wt.% Cu and 53 wt.% Pd–47 wt.% Cu) was evaluated using transient flux measurements at temperatures ranging from 603 to 1123 K and pressures up to 620 kPa both in the presence and absence of 1000 ppm H 2 S. Sulfur resistance, as evidenced by no significant(More)
The high-pressure (100-2500 kPa) hydrogen permeance of two membranes, each composed of a thin palladium film (~22 μm) deposited on the oxidized surface of a porous stainless steel tubular substrate (0.2 μm grade support) has been determined over the 623 – 723 K temperature range. The hydrogen flux was proportional to the H 2 partial pressure in the(More)
Metal membranes play a vital role in hydrogen purification. Defect-free membranes can exhibit effectively infinite selectivity but must also provide high fluxes, resistance to poisoning, long operational lifetimes, and low cost. Alloying offers one route to improve on membranes based on pure metals such as palladium. We show how ab initio calculations and(More)
The high-temperature rate of reaction of the homogeneous, reverse water-gas shift reaction, rWGSR, has been evaluated in quartz reactors with rapid feed pre-heating at low-pressure and high-pressure conditions. The form of the power-law rate expression was consistent with the Bradford mechanism. The Arrhenius expressions for the reaction rate constant(More)
14 The hydrogen permeability of bulk tantalum and tantalum coated with thin films of palladium was measured at temperatures from 623 to 1173 K and hydrogen partial pressures from 0.1 to 2.6 MPa in a flowing gas system. Palladium coatings were deposited by both electroless plating (1–2 ␮m thick Pd layer) and cold plasma-discharge sputtering with two(More)
  • Angel Cugini, ANGELA VICTORIA CUGINI, Angela Victoria Cugini, Alan J. Lesser, Anthony Cugini
  • 2015
DEDICATION To my father, Anthony Cugini v ACKNOWLEDGEMENTS I first would like to thank my advisor, Professor Alan Lesser. One of my favorite things about Professor Lesser is learning to be inventive in lab. He always encourages his students to build your own devices to get creative measurements of polymers. I got to work with power tools and the machine(More)
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