Anthony D Ledet

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We have synthesized the first diamidocarbene (DAC)-supported borenium salt, [][OTf], which was found to readily undergo two sequential 1-electron reductions. The first reduction forms a thermally robust, crystalline boryl-substituted DAC-centred radical () which has been fully characterized by XRD, EPR spectroscopy, and DFT analyses. The 1-electron(More)
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