Anna Kanegae

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In this Communication, we report on the development of a ratiometric fluorescent probe for silver(I) ions (Ag(I)) based on an arene-metal ion interaction. The probe selectively senses Ag(I) among various metal ions with a large-emission red shift under aqueous conditions, enabling the selective ratiometric detection of Ag(I). X-ray crystallography and NMR(More)
We report the design and development of a fluorescent Cd(II) ion complex that is capable of the ratiometric detection of H2 S in living cells. This probe exploits the metal-ion-induced emission red shift resulting from direct contact between the aromatic ring of a fluorophore and a metal ion (i.e., arene-metal-ion or "AM" contact). The Cd(II) complex(More)
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