Anitha Boddeda

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Magic blue (MB+˙ SbCl6− salt), i.e. tris-4-bromophenylamminium cation radical, is a routinely employed one-electron oxidant that slowly decomposes in the solid state upon storage to form so called ‘blues brothers’, which often complicate the quantitative analyses of the oxidation processes. Herein, we disclose the identity of the main ‘blues brother’ as the(More)
S2. Calibration of Computational Approach for iAPPn/iAPPn Series ......................................... 4 S2.1. Oxidation potentials ................................................................................................................................. 5 S2.2. Electronic excitation energies of iAPPn(More)
Koopmans' paradigm states that electron loss occurs from HOMO, thus forming the basis for the observed linear relationships between HOMO/IP, HOMO/Eox, and IP/Eox. In cases where a molecule undergoes dramatic structural reorganization upon 1-electron oxidation, the IP/Eox relationship does not hold, and the origin of which is not understood. For example,(More)
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