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Head-to-tail carbon disulfide dimers of composition M(C 2 S 4 )(C 2 H 4 )(PMe 3 ) 3 (M=Mo, W) have been prepared by action of CS 2 on the ethylene complexes trans-M(C 2 H 4 ) 2 (PMe 3 ) 4 (M=Mo, W).(More)