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Despite intensive study of the pyrolysis of C/sub 7/H/sub 8/ compounds, the methylenecyclohexadienes, o- and p-isotoluenes, 1 and 2, respectively, have received little attention. Both 1 and 2 are ca.… Continue Reading
3-Methylene-1,4-cyclohexadiene, 1,5-methylene-1,3-cyclohexadiene, 2, 1-methylene-1,4-dihydronaphthalene, 5, and 9-methylene-9,10-dihydroanthracene, 8, react with second-order kinetics in benzene… Continue Reading
Fluoride ion induced generation of isobutylidene from isopropyl trimethylsilyl ketone enol triflate in the presence of 6,6-dimethylfulvene gives the [2.2]-m-cyclophane dimer of… Continue Reading